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However, Glutathione is poorly absorbed from the gastrointestinal tract, and foods rich in glutathione do not appear to contribute to increases in intracellular glutathione levels

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For this interaction to occur, the structural requirement in the enzyme is the presence of a nucleophilic amino acid side-chain close to the glutathione-docking motif and in a crucial position to interact with the electrophilic motif of glutathione acrylate, as shown in Scheme 9